![]() ![]() Hyun Suk Lim, Yikyeom Kim, Dohyung Kang, Minbeom Lee, Ayeong Jo, Jae W.Single Atom Catalysts for Selective Methane Oxidation to Oxygenates. Perspective on Sorption Enhanced Bifunctional Catalysts to Produce Hydrocarbons. ![]() Seongbin Jo, Luz Cruz, Soham Shah, Somchate Wasantwisut, Annette Phan, Kandis Leslie Gilliard-AbdulAziz.Computational Study of Zn Single-Atom Catalysts on In2O3 Nanomaterials for Direct Synthesis of Acetic Acid from CH4 and CO2. ACS Applied Materials & Interfaces 2022, 14 Rational Design of Metal-Alkoxide-Functionalized Metal–Organic Frameworks for Synergistic Dual Activation of CH4 and CO2 toward Acetic Acid Synthesis. This article is cited by 29 publications. We conclude by identifying opportunities for improving the efficiency of heterogeneous catalysts for this important reaction. We also compare different technologies, including catalyst pretreatment, preactivation with CO 2, tandem reaction, and plasma-driven catalysis for the CH 4 and CO 2 conversion. We discuss how the active sites and transition states can be modified by the location of metal sites, the framework environment, and the promotion effect of different acid sites. The differences in the metal oxidation state may affect the adsorption of CH 4 and CO 2 and consequently change the activation barriers for the dissociation of the C–H bond of CH 4 and the C–C coupling reaction. We elucidate how Cu- and Zn-based catalysts with different structures are used for the activation of CH 4 and CO 2. This article provides a critical assessment of the progress in this catalytic reaction from the perspective of identifying and constructing the active sites. The reaction of CH 4 and CO 2 to produce acetic acid is an atom-efficient way for using carbon resources and for mitigating CO 2 emissions. ![]()
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